The draw for the last eight takes place on Friday and UEFA have confirmed that if both sides are drawn to play at home in the same week, United's tie would have to be reversed.
But Mourinho is only banking on two being in the semi-finals as he revealed his preferred last eight selections.
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If the reds go through they will face Barcelona or Man Utd in the semi final. The five-time Ballon' dor victor promised the Barcelona fans after the finals match of last season that his side would be gunning for glory in this competition.
"Following a decision made by relevant local authorities, Manchester City and Manchester United can not play at home on the same night, nor on consecutive nights", UEFA said.
Maurizio Sarri's men looked pretty toothless at home to Wolves last week and needed a stoppage-time goal to salvage a draw, and their four previous Premier League away games resulted in three defeats by an aggregate score of 12-0, and a 2-1 win at nearly relegated Fulham.
It will probably come as a surprise that both Premier League teams are considered to have a better chance than Barcelona and Juventus, who pull up in third and fourth respectively. Chelsea is especially happy that its draw of Slavia Prague, who it will not overlook, allows it some flexibility with the Liverpool league fixture sandwiched in between.
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"I'm coming back to my second home".
"But I would do two matches between English teams, which would mean two teams would be in the semi-finals".
Last year, Cristiano Ronaldo was bought by Juventus, a team which has lost two finals in the past four years, to end that 23-year wait. "You are expecting to play one of the big boys at this stage". "So it is nice that I will now face him for real".
This is the first season since 2009/10 that defending champions Real Madrid did not progress beyond the round of 16, which means there will be a new victor of the Champions League after Los Blancos won the past three consecutive finals.
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The Pittsburgh Steelers are clearly worse as Ben Roethlisberger is another year older, and Antonio Brown is now with the Raiders. Whether you're a United fan, a Liverpool fan, or support your local team, we've all felt the grief of losing a key player.
Georginio Wijnaldum reflected on Liverpool's pairing with FC Porto in the Champions League quarter-finals and outlined why he believes it'll prove a "different" tie to the meeting last term.
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