Windsor-Essex and Chatham-Kent are under freezing rain warnings.
A combination of rain, freezing rain and snow could make for slippery surfaces and traffic disruptions in southwest and central Quebec starting Sunday afternoon and continuing into the evening.
The agency said a brief period of snow could be expected following the freezing rain, but not enough for significant accumulation.
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It should be around for several hours before tapering off Sunday night and turning back to light snow.
Parts of Quebec, including Montreal, are in for several hours of freezing rain, making travel hard and unsafe.
Motorists should exercise caution, as road surfaces may become icy and slippery.
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They also advised for people to maintain a safe distance when driving and to a lot more time for commutes.
Brace for it. Freezing rain is on the way, warns Environment Canada. "Poor weather conditions may contribute to transportation delays".
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